Solvent Effects on Kinetics of the Reaction between 2-Chloro- 3,5-dinitropyridine and Aniline in Aqueous and Alcoholic Solutions of [bmim]BF4

Harifi-Mood, Ali Reza and Habibi-Yangjeh, Aziz and Gholami, Mohammed Reza (2008) Solvent Effects on Kinetics of the Reaction between 2-Chloro- 3,5-dinitropyridine and Aniline in Aqueous and Alcoholic Solutions of [bmim]BF4. In: 11th Iranian Physical Chemistry Seminar-July 2008.

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Abstract

Room-temperature ionic liquids (RTILs) have recently gathered up increasing attention as environmentally benign alternatives to conventional organic solvents in a variety of synthetic, catalytic, and electrochemical applications, a result of their unique physical and chemical properties and the relative ease with which these properties can be fine-tuned by altering the cationic or anionic moieties comprising the RTILs. They continue to excite interest for a number of reasons. The first arises from the claim that ionic liquids are environmentally friendly solvents, particularly because they have very low vapor pressures under ambient conditions. Secondly, they might provide improved reactivities in a number of chemical processes. Finally, the fact that a wide range of cations and anions can be employed gives chemists the potential to design the solvents with specific properties. In such case, ionic liquids are described as “designer solvents”. In this work the solvent effects on kinetics of nucleophilic heteroatomic substitution reaction of 2-chloro-3,5-dinitropyridine with aniline was studied in aqueous and alcoholic solution of 1-(1-butyl)-3-methyl imidazolium tetrafluoroborate ([bmim]BF4) at 25°C.

Item Type: Conference or Workshop Item (Poster)
Persian Title: Solvent Effects on Kinetics of the Reaction between 2-Chloro- 3,5-dinitropyridine and Aniline in Aqueous and Alcoholic Solutions of [bmim]BF4
Persian Abstract: -
Subjects: Divisions > Conferences > 11th Iranian Physical Chemistry Seminar- July 2008
Conferences > 11th Iranian Physical Chemistry Seminar- July 2008
Divisions: Conferences > 11th Iranian Physical Chemistry Seminar- July 2008
Subjects > Conferences > 11th Iranian Physical Chemistry Seminar- July 2008
Date Deposited: 17 Jun 2019 05:03
Last Modified: 17 Jun 2019 05:03
URI: http://repository.uma.ac.ir/id/eprint/6792

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