Theoretical study of [1,5]-hydrogen shift in substituted 1,8a- dihydronaphenthalene

Ebrahimi, Ali and Habibi Khorasani, Mostafa and Gholeepoor, Ali Reza (2008) Theoretical study of [1,5]-hydrogen shift in substituted 1,8a- dihydronaphenthalene. In: 11th Iranian Physical Chemistry Seminar-July 2008, July 2008, Ardabil, Iran.

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Abstract

The [1,5]-hydrogen shift stimulated many mechanistic studies [1.2] and has found numerous applications in organic synthesis[3,4]. This reaction usually proceeds by concerted pathway involving an aromatic transition state[5,6,7]. The effect of aromatic stabilization on the rates of [1,5]- hydrogen shift were previously estimated experimentally and theoretically. Not only the activation energy but also the shape and the position of the reaction barrier can be efficiently controlled by change in aromaticity.

Item Type: Conference or Workshop Item (Paper)
Persian Title: Theoretical study of [1,5]-hydrogen shift in substituted 1,8a- dihydronaphenthalene
Persian Abstract: -
Subjects: Divisions > Conferences > 11th Iranian Physical Chemistry Seminar- July 2008
Conferences > 11th Iranian Physical Chemistry Seminar- July 2008
Divisions: Conferences > 11th Iranian Physical Chemistry Seminar- July 2008
Subjects > Conferences > 11th Iranian Physical Chemistry Seminar- July 2008
Date Deposited: 17 Jun 2019 05:24
Last Modified: 17 Jun 2019 05:24
URI: http://repository.uma.ac.ir/id/eprint/6810

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